Whether the MC is trying to change his ways or trying to play the part, the role he's been cast as is the villain!
There may be a few relating to this topic but not specifically the Mc being the villain but that's only if the plot particularly stands out. So for the most part its hopefully just going to be mainly a villain mc.

Ill try my best to label the ones that don't have the MC as a villain

(The number of times I've written "villain" slightly exceeded my expectations, not by a lot, but still, more than I had in mind)